Second shooter for Paris FC during the penalty shootout, Clara Mateo takes her head in her hands.
His shot was blocked by the AS Roma goalkeeper.
The French international, who comes out of an excellent Euro with the Blue and author of a double Thursday against the Swiss Servette (3-0) was the only one to fail during this session.
The Italians went faultless and on the PFC side, Gaëtane Thiney, Ouleymata Sarr, Thea Greboval and Anaïg Butel succeeded in their attempts.
It's terrible, cruel for the girls of Paris FC.
The adventure in the Champions League therefore ended in Glasgow after this penalty shootout in the final of the preliminary round.
The play-offs (go September 20-21, return September 27-28) will therefore take place without them.
A cruel disappointment for the return of the PFC to the European scene after the epic of Juvisy, the club which it absorbed in 2017.
Two hits on the bar in overtime
During the 120 minutes of a very intense and sometimes tense fight, each team had its chance.
Paris FC had twice found the bar in extra time by Louise Fleury (94th) and Ouleymata Sarr (114th).
But the Italians had also found the bar (77th).
Gaëtane Thiney (72nd) and Sophie Vaysse (99th) also saved AS Roma attempts on the line.
After the defeat on Saturday in L2 at Niort (2-1), the weekend will have been rotten until the end for Paris FC.
Match sheet
PARIS FC - AS ROMA 4-5 on pens (0-0).
Paris FC:
Nnadozize - Soyer, Butel, Greboval Aigbobun - Vaysse, Corboz (Le Mouël, 56th), Thiney (cap.) - Mateo, Bourdieu (Fleury, 62nd), Sarr.
Entr.
: Soubeyrand.